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BONDING PROPERTIES OF ALKENES

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15/07/2017
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As compared to a single C-C bond, the double C=C bond bears a planar geometry, shorter bond lenghts and higher bond energy.
Image Angles, lenghts and 
energy (kcal/mol)
Image Angles, lenghts and 
energy (kcal/mol)
PROPANEPROPENE
The C(sp3)-C(sp2) bonds have a slight dipole moment because the olefin sp2 carbons are understood to be slightly more electronegative than the alifatic sp3 ones.  This is explained due to the higher s character of the sp2 hybridization (one third) as compared to the sp3 (one quarter). The electrons in a sp2 orbital are slightly closer to the atomic nucleus and hence more attracted.

But polarity mainly depends on the E / Z stereochemistry of the olefin:

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Alkenes cannot actually be catalogued as acids but, in relative terms, they are a million times more acidic than the corresponding alkanes.

 This is proof of the higher electronegativity of the sp2 carbons relative to the sp3 ones.
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The electron pair of the alkene carbanion resides in a sp2 orbital with larger s character and thus closer to the atomic nucleus. This fact may stabilize the negative charge what helps us to explain the acidity difference between alkenes and alkanes.