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SolutionsIonic Structures

1. Positive and negative ions

State the ions that make up K2O, Na2S, NaI and CaBr2.

  1. K2O: K+ and O2−
  2. Na2S: Na+ and S2−
  3. NaI: Na+ and I−
  4. CaBr2: Ca2+ and Br−

Metals form the positive ions and nonmetals the negative ones.

2. LiF or LiI

Which melts at a higher temperature, LiF or LiI? Why?

LiF. The Li+ and F− ions are more similar in size (r+/r− closer to 1): they pack better, the lattice energy is higher and a higher temperature is needed to melt it.

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