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Problems and exercisesAlpha Halogenation

1. An amino acid from an acid

Which product does 3-methylbutanoic acid give in the Hell-Volhard-Zelinsky reaction (Br2, red P, then H2O)? And if that product is treated with an excess of ammonia?

2. An acid that does not react

Why does 2,2-dimethylpropanoic acid not undergo the Hell-Volhard-Zelinsky reaction?

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