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SolutionsNitriles

1. Why with the derivatives?

Why are nitriles studied together with carboxylic acid derivatives?

Their carbon has the same oxidation state (+3) as that of acids, and hydrolysis turns them into carboxylic acids (via the amides).

2. Geometry

What is the hybridization of the carbon and nitrogen of the C≡N group? What angle does the R–C≡N group form?

Both are sp; the R–C≡N group is linear (180°), like an alkyne.

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