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SolutionsNomenclature

1. Name them

Name: a) CH3CH2COCl; b) C6H5COCl; c) (CH3)2CHCOBr; d) ClOC–CH2–COCl.

  1. Propanoyl chloride.
  2. Benzoyl chloride.
  3. 2-Methylpropanoyl bromide.
  4. Propanedioyl dichloride (malonyl chloride).

2. As a substituent

Name HOOC–CH2–CH2–COCl, in which the acid is the principal function.

3-(Chlorocarbonyl)propanoic acid; it is also named with the prefix "chloroformyl": 3-chloroformylpropanoic acid.

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