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Problems and exercisesPhysical and Bond Properties

1. Boiling point

Acetyl chloride (mass 78.5) boils at 51 °C and acetic acid (mass 60) at 118 °C. Explain.

2. Resonance

The C–Cl bond of acetyl chloride (1.743 Å) is almost the same as in chloromethane (1.741 Å). What does this say about the third resonance form?

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