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Problems and exercisesStructure and Nomenclature

1. General formula

Write the molecular formulas of cyclopentane, methylcyclohexane and decalin (two fused six-membered rings). How many hydrogens does the formula lose for each ring?

2. Name these cycloalkanes

  1. A cyclohexane bearing an ethyl group
  2. A cyclopentane with two methyl groups on adjacent carbons
  3. A cyclohexane with an ethyl and a methyl group at positions 1 and 3
  4. A cyclobutane bearing an isopropyl group

3. Cis/trans isomerism

Which of these compounds show geometrical isomerism?

  1. 1,1-Dimethylcyclohexane
  2. 1,2-Dimethylcyclopropane
  3. 1,4-Dimethylcyclohexane
  4. Methylcyclopentane

4. Stereoisomers of 1,2-dimethylcyclopropane

How many stereoisomers does 1,2-dimethylcyclopropane have? Is any of them chiral?

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