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Problems and exercisesReduction Reactions

1. Diphenylacetylene

Predict the result of the following reactions:

Diphenylacetylene with Na/NH₃ and with H₂ and Lindlar catalyst

2. Synthesis of a pheromone

How would you prepare (Z)-tricos-9-ene, CH3(CH2)7CH=CH(CH2)12CH3, the sex pheromone of the housefly, from an alkyne?

3. Why does it stop?

Why does hydrogenation with the Lindlar catalyst stop at the alkene and not go on to the alkane?

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