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Nomenclature

The alcohol function has in general low priority when found with other functional groups. It is frequently named as a secondary function.

Priority order of functional groups: alkane, halide, alkene, alcohol, ketone, aldehyde and acid

MAIN FUNCTION

The main chain is the longest containing the hydroxyl group (OH).

The name of the main chain is suffixed with -ol.

The OH localizer should be the lowest possible number.

Examples of alcohol nomenclature: 3,6,7-trimethyl-4-nonanol, cyclohexanol, cis-3-bromocyclohexanol, 3-buten-1-ol, 4-methyl-2-cyclohexen-1-ol, 3-cyclopentenol and 2-aminoethanol

Non-systematic, trivial names can be used in the case of common, simple alcohols.

SECONDARY FUNCTION

Each OH group is named as hydroxy.

If there are more than one, the prefixes di-, tri-, tetra-, etc. are used.

The localizer number(s) should be the lowest possible regarding the main function.

OH as a secondary function: 4-hydroxycyclohexanone and 2,3-dihydroxypropionic acid

Depending on the substitution of the carbon bearing the OH group, an alcohol will be:

Primary (–CH2–OH), secondary (>CH–OH) and tertiary (>C(–)–OH) alcohols