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Problems and exercisesAmines, anilines and other nitrogen functions

1. Primary, secondary, tertiary or quaternary

Classify each nitrogen compound:

  1. CH3CH2NH2
  2. (CH3CH2)2NH
  3. (CH3)3N
  4. (CH3)4N+ Cl−
  5. Piperidine
  6. C6H5NH2

2. Base and nucleophile

Which structural feature explains why amines are both bases and nucleophiles? Give an example of each behaviour.

3. Nitrogen families

Give the oxidation state of nitrogen in: CH3NH2, CH3N=C=O, CH3N3 (the atom bonded to carbon) and CH3NO2.

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