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Problems and exercisesOxidation

1. Aldehydes and ketones versus oxidants

Give the product of the oxidation of: a) 4-hydroxybenzaldehyde with Ag2O; b) cyclopentanone with hot KMnO4; c) cyclohexanone with peroxybenzoic acid.

2. Which group migrates?

Which ester is obtained in the Baeyer-Villiger oxidation of: a) acetophenone; b) cyclohexyl methyl ketone?

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