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Problems and exercisesReactivity

1. Aldehyde or ketone

Rank by reactivity towards nucleophilic addition: acetone, formaldehyde, acetaldehyde and di-tert-butyl ketone. Explain.

2. Where does each reagent attack?

Indicate which center of butanone takes part in its reaction with: a) NaBH4; b) LDA; c) H2SO4 (protonation); d) Br2 in acid.

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