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Problems and exercisesUnimolecular Elimination

1. Substitution and elimination

What products are obtained by heating tert-butyl chloride in methanol?

2. The leaving group

tert-Butyl chloride, bromide and iodide give the same ether/alkene ratio in methanol. Why?

3. Two alkenes

Which alkenes are formed by E1 from 2-bromo-2-methylbutane? Which is the major one?

4. Kinetics

Write the rate law of an E1 reaction and explain its order.

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