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Problems and exercisesConcept of Leaving Group

1. Order the halides

Order from best to worst leaving group: I−, F−, Cl− and Br−.

2. HO− and H2O

Why is hydroxide a poor leaving group and water a good one? What does this mean for alcohols?

3. Sulfonates

Why are sulfonates, RSO3−, excellent leaving groups?

4. Which reacts faster?

Which will react faster with NaCN by SN2, CH3CH2Cl or CH3CH2I?

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