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Problems and exercisesNomenclature

1. Name these halides

  1. CH3CH2CH2Br
  2. (CH3)2CHCl
  3. CH3CHBrCH2CH3
  4. (CH3)3CI
  5. CH2Cl2
  6. CHCl3

2. Write the formula

  1. 1-Bromo-2-methylpropane
  2. 1,2-Dichloroethane
  3. 3-Bromo-2-chloropentane
  4. Iodocyclohexane

3. Primary, secondary and tertiary

Classify these alkyl halides:

  1. 1-Chloro-2-methylpropane
  2. 2-Bromobutane
  3. 2-Chloro-2-methylbutane
  4. Chloromethane
  5. Bromocyclohexane

4. The order of prefixes

Why is CF3CH2CHClCH(CH3)CH2CH2CH(CH3)2 named 3-chloro-1,1,1-trifluoro-4,7-dimethyloctane and not 1,1,1-trifluoro-3-chloro-4,7-dimethyloctane?

5. Alkyl, aryl or alkenyl?

  1. Bromobenzene
  2. Vinyl chloride, CH2=CHCl
  3. Benzyl bromide, C6H5CH2Br
  4. 3-Chlorocyclohexene

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