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Problems and exercisesDirecting Effects

1. Energy diagrams

Give a real example of the nitration of a monosubstituted benzene for each of the qualitative energy diagrams. Take the energy profile of the nitration of benzene as reference.

Four qualitative energy diagrams for the nitration of a monosubstituted benzene X–C₆H₅ (ortho, meta and para pathways), compared with that of the nitration of benzene

2. Activating or deactivating?

Classify these groups as activating or deactivating and as ortho-para or meta directors: –OCH3, –CHO, –Br, –CH2CH3, –SO3H, –NHCOCH3, –CN.

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