Problems and exercisesOxidation of Alcohols
1. Products
Give the oxidation product of each alcohol:
- 1-Butanol with PCC in CH2Cl2
- 1-Butanol with KMnO4 in basic medium (and acidification)
- 2-Butanol with H2CrO4
- 2-Methyl-2-butanol with H2CrO4
2. Stopping at the aldehyde
Why is it hard to obtain aldehydes by oxidizing primary alcohols in water?
3. Oxidation state of chromium
How does the oxidation state of chromium change when a secondary alcohol is oxidized with chromic acid?