Problems and exercisesCarbonyl Addition
1. Products
- Benzaldehyde + CH3NH2
- Acetone + hydroxylamine (NH2OH)
- Cyclohexanone + pyrrolidine (secondary amine)
- Acetaldehyde + excess hydrazine
2. The optimum pH
Imine formation is fastest at pH ≈ 4-5. Why is it slower in strongly acidic and in basic media?
3. Hydrolysis
What is obtained when the N-ethylimine of butanone is treated with water and dilute acid? Why?