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Problems and exercisesCarbonyl Addition

1. Products

  1. Benzaldehyde + CH3NH2
  2. Acetone + hydroxylamine (NH2OH)
  3. Cyclohexanone + pyrrolidine (secondary amine)
  4. Acetaldehyde + excess hydrazine

2. The optimum pH

Imine formation is fastest at pH ≈ 4-5. Why is it slower in strongly acidic and in basic media?

3. Hydrolysis

What is obtained when the N-ethylimine of butanone is treated with water and dilute acid? Why?

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