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Preparation

The most straightforward manner to get an aniline is by nitro group reduction:

Reduction of nitrobenzene to aniline with Zn(Hg)/HCl, H₂/Ni or Fe/HCl, and the reverse oxidation with CF₃CO₃H: the nitro group is deactivating and meta-directing; the amino group, activating and ortho-para-directing

The conversion of the nitro group into amine reverses the electronic properties of the aromatic ring, making its reactivity very different. This fact will be treated in detail in the aromatic compounds' chapter.

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