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Problems and exercisesReactivity

1. Complete the reactions

  1. CH3CH2NH2 + CH3COCl (with pyridine)
  2. Cyclohexanone + CH3NH2 (acid catalyst)
  3. (CH3)2NH + NaNO2/HCl
  4. CH3CH2CH2N(CH3)3+ HO−, heat

2. Amide versus amine

Why is acetamide not basic, while ethylamine is?

3. Tell the amines apart

How would you distinguish a primary, a secondary and a tertiary aliphatic amine with nitrous acid?

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